By Marianna Kontopoulou
Explore polymer rheology from an commercial standpoint
Presenting cutting-edge polymer rheology as saw by way of well-recognized authors, Applied Polymer Rheology: Polymeric Fluids with commercial Applications is designed to assist readers comprehend the connection among molecular constitution and the movement habit of polymers. specifically, it makes a speciality of polymeric structures that elicit detailed recognition from industry.
Providing a entire evaluation of the rheological features of polymeric fluids, the ebook bridges the distance among idea and practice/application, allowing readers to work out the relationship among molecular constitution and the habit of the polymers studied. starting with a dialogue of the houses, processability, and processing aids of particular polymers, later chapters research stuffed polymers and composites, and the theoretical framework upon which their research relies. a variety of structures containing microstructure are awarded as a result, with the ultimate bankruptcy introducing paste extrusion of polytetrafluoroethylene paste.
An beneficial reference advisor that covers the literature and substantial array of technical ways to polymer rheology, Applied Polymer Rheology's insurance of polymeric fluids of curiosity to make it a necessary source for plastics, polymer, and chemical engineers, fabrics scientists, polymer chemists, and polymer physicists to take advantage of whilst studying findings and making plans experiments.
Chapter 1 uncomplicated recommendations in Polymer soften Rheology and Their value in Processing (pages 1–27): John Vlachopoulos and Nickolas Polychronopoulos
Chapter 2 Polymer Processing ingredients for soften Fracture keep watch over (pages 29–58): Savvas G. Hatzikiriakos and Kalman B. Migler
Chapter three Branched Polyolefins (pages 59–112): Alexandros D. Gotsis
Chapter four constitution and Rheology of Fiber Suspensions (pages 113–151): Aaron P. R. Eberle, Kevin Ortman and Donald G. Baird
Chapter five Rheology and Processing of Polymer Nanocomposites (pages 153–177): Ramanan Krishnamoorti and Tirtha Chatterjee
Chapter 6 Rheology of Wood–Plastics Composites (pages 179–208): Tieqi Li
Chapter 7 Block Copolymers in exterior Fields: Rheology, Flow?Induced Phenomena, and functions (pages 209–239): Michel Cloitre and Dimitris Vlassopoulos
Chapter eight Reactive structures and Thermoplastic Vulcanizates (pages 241–261): Philippe Cassagnau, Gregory Martin and Claire Barres
Chapter nine constitution and Rheology of Polymer Composites Containing Thermotropic Liquid Crystalline Polymers (pages 263–264): Jiasong He
Chapter 10 Electrorheological Fluids: fabrics and Rheology (pages 285–302): Fei Fei Fang and Hyoung Jin Choi
Chapter eleven Rheology and Processing of Polytetrafluoroethylene Paste (pages 303–334): Savvas G. Hatzikiriakos
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Additional resources for Applied Polymer Rheology: Polymeric Fluids with Industrial Applications
T. J. MacKnight, Introduction to Polymer Viscoelasticity, Wiley, New York, 2005. 12. M. G. Larson, Structure and Rheology of Molten Polymers, Hanser, Munich, 2006. 13. K. Gupta, Polymer and Composite Rheology, Marcel Dekker, New York, 2000. 14. L. Leblanc, Filled Polymers, CRC Press, Boca Raton, 2010. 15. J. R. , The SPE Guide on Extrusion Technology and Troubleshooting, Society of Plastics Engineers, Brookﬁeld, CT, 2001. 16. S. Middleman, Fundamentals of Polymer Processing, McGraw-Hill, New York, 1977.
2 Fluoropolymer PPA Technology . . . . . . . . . . . . . . . . 3 Mechanisms of Instabilities, Slippage and the Role of PPAs . . . . . . 1 Sharkskin and Other Melt Fracture Phenomena . . . . . . . . 2 Slippage . . . . . . . . . . . . . . . . . . . . . . 3 Precoating Dies with PPAs . . . . . . . . . . . . . . . 4 Coating Process of Fluoropolymers . . . . . . . . . . . . 5 Coating Thickness and a Simple Coating Model. . . .
1% PPA/LLDPE blend (b). Reprinted with permission from Ref. 29. present. In the presence of the PPA, both the sharkskin and the stick-slip instability disappear, while the gross melt fracture regime still occurs. Similar results for a variety of polyoleﬁns have been published [1, 5, 10, 12, 14, 17, 20, 21, 24–26]. The reduced shear stress at a given throughput is a sign of slippage. However, in one study it was found that a DFL ﬂuoropolymer PPA promoted adhesion, while having no effect on the ﬂow curve .