Handbook of Condensation Thermoplastic Elastomers by Stoyko Fakirov PDF

By Stoyko Fakirov

Reporting at the paintings of a global staff of scientists actively concerned with the learn of thermoplastic elastomers (TPE) in response to polyesters, polyamides, and polyurethanes, this publication is the 1st to supply an in depth description of condensation TPE with shut recognition paid to polyamide-based structures. Reflecting the expanding value of TPE as engineering plastics, the authors talk about the widened software possibilities through getting ready platforms with a number of chemical compositions and molecular constructions as (semi-) interpenetrating networks. The contents additionally conceal the chemical features, actual constitution and homes, existence cycle evaluate, and recycling chances in addition to such exact "smart" homes just like the form reminiscence impression of the 3 sessions of thermoplastic elastomers.

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Reactive processings The corresponding literature was reviewed by Prut and Zelenetskii [146] and an important part is related to dynamic vulcanization; some of the references provide a deep insight in the chemical evolution, particularly in side reactions [147,148]. The morphology of thermoplastic vulcanizates during processing drastically depends on temperature and shear and, to a lesser extent, on the screw rate [149]. 7. Degradation in processing Endres et al. [150] carried out a fundamental study of the thermal decomposition of TPEs under thermoplastic processing conditions, more particularly of the respective kinetics, and an equation was given describing the thermal degradation of polyurethanes upon extrusion.

TPE: Creation, Development, Position Among Organic Materials 25 90. Geiger T and Stadler R (1998) Investigation of cluster formation in thermoreversible networks, Wiley Polym Networks Group Rev Ser 1:129–138. 91. Nair B R, Gregoriou V G and Hammond P T (2000) FT-IR studies of side chain liquid crystalline thermoplastic elastomers, Polymer 41:2961–2970. 92. Wang T-L and Huang F-J (2000) Preparation and characterization of novel thermoplastic elastomers by step/chain transformation polymerization, Polymer 41:5219–5228.

Controlled radical polymerization The discovery of the controlled radical polymerization (CRP) offered additional possibilities in the chemistry of TPEs [52–54]. CRP was used in both graft and block copolymer preparation and extensively reviewed by Matyjaszewski [55] and Mayes et al. [56]. It allows the easy preparation of novel environmentally friendly materials, such as polar TPEs; it can be carried out in the bulk or in water and requires only a modest deoxygenation of the reaction mixture. Atom transfer polymerization (ATRP) is one of the most important aspects of CRP; it was developed by Matyjaszewski and rests on an equilibrium between active and dormant species [57].

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