Photostabilization of Polymers: Priciples and Applications by J.F. Rabek PDF

By J.F. Rabek

During the final twenty years, the construction of polymers and plastics has been expanding quickly. regardless of constructing new polymers and polymeric fabrics, simply 40-60 are used commercially on a wide scale. it's been predicted that 1/2 the once a year creation of polymers is hired outside. expanding the soundness of polymers and plastics in the direction of warmth, mild, atmospheric oxygen and different environmental brokers and weathering stipulations has continually been an important challenge. The photochemical instability of such a lot of polymers limits them to outside software, the place they're photograph­ degraded quick over classes starting from months to some years. To the depression of technologists and shoppers alike, photodegrada­ tion and environmental growing older of polymers ensue a lot swifter than may be anticipated from wisdom amassed in laboratories. in lots of circumstances, greater equipment of instruction and purification of either monomers and polymers yield items of higher caliber and better resistance to light and heat. although, with out stabilization of polymers by means of applica­ tion of antioxidants (to reduce thermal oxidative degradation) and photostabilizers (to reduce photo-oxidative degradation) it might be very unlikely to hire polymers and plastics in daily use.

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L is the thickness in which diffusion of oxygen is not a limiting factor in the oxidation reaction, and 5 is the diffusioncontrolled lone. 389 34 PHOTOSTABILIZATION OF POLYMERS: PRINCIPLES AND APPLICATIONS For any point in the thick polymer film equation (1. 79) is valid: ac~~, t) = D a2~~; t) _ kC(x, t) (1. 79) where C(x, t) = concentration of oxygen at a given depth x and a given time t; x = direction defined as perpendicular to the facets of the film; t = time of reaction; k = first-order rate constant; = oxygen diffusion constant in a polymer film.

36 PHOTOSTABILIZATION OF POLYMERS: PRINCIPLES AND APPLICATIONS (iv) Between small radicals and macromolecules which involve hydrogen abstraction from the polymer backbone (and/or side groups). In this case all small radicals will have C-H bonds in the immediate vicinity, there is no dependence on diffusion and rates would be similar to fluid solution rates. (v) Between all available polymer radicals. In a polymer matrix the mobility of polymer radicals is very restricted. The bimolecular rates are reduced by a factor of about 10- 4 relative to fluid solution rates.

5. 315 crystalline phase leads to an increase in free volume in the amorphous phase. It is worth noting that measured values of solubilities of additives in a polymer vary according to the methods used (Fig. 2). 3 Diffusion of Additives in a Polymer Matrix The following factors affect the diffusion of additives in a polymer matrix: 801 (i) Temperature. The diffusion coefficient (D) depends on temperature (increasing with temperature) according to the "LOPE, Low-density polyethylene. 2 Solubility parameters (5) of antioxidants in polyolefins at two temperatures315 180 419,420 956 180 419 799 180 799 References ~ ~ ~ E ~ ~ ~ ~ 2l ~ ~ = ~ ~ a!

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